Hydrogen Peroxide Analyser – PeroxiSense

The PeroxiSense sensors can come equipped to automatically clean themselves at user defined intervals, with all the benefits of no operator intervention for up to 6 months. The AutoFlush is particularly useful in food preparation, pulp and paper, and many applications where there is likely to be a build up of solids in the sample. For more information about AutoFlush click here.

The whole range of PeroxiSense Hydrogen Peroxide Monitors and Controllers can be fitted with additional sensors such as ORP or pH. Please ask your local distributor for more details.

The CRONOS^® and CRIUS^®4.0 controllers can be equipped with data-logging, relay outputs, analogue outputs and serial communications such as: Ethernet, Modbus and Profibus. Remote monitoring of the instruments (including remote access to all control options) is available via the internet over GPRS and via a LAN. In fact the CRIUS^®4.0 PeroxiSense monitor has all the options you could want, whilst the CRONOS^® provides a low cost alternative and is particularly great value for money!

Membraned sensors come with many advantages over non-membraned sensors such as higher resolutions, fewer interferents and a greatly reduced effect of flow rate changes. These advantages can make a huge difference to the bottom line, particularly if the cost of the chemical being dosed is quite high. For free chlorine sensors, using a membrane can make your measurement much less dependent on pH (if you are using sensors from Pi), meaning your measurement is a more accurate reflection of chlorine residual.


As such, membraned sensors are now largely the norm in residual chlorine measurement and are also prevalent for chlorine dioxide and ozone monitors, but did you know that…

…membraned sensors are sensitive to changes in pressure?

…flow cell outlets can airlock even when water is flowing through them?

…membraned sensors can still be used when the outlet does not go to drain?

…Pi has engineered and designed solutions to all of these potential issues?

Sensitivity to pressure

Membraned sensors do have one property that needs to be carefully managed; they are sensitive to pressure. Pi was an early adopter of membrane technology, so we know that the installation of these sensors is just as important as the sensor itself. In fact, the same sensors in different flow cells can give very different results.


In order to prevent pressure variations affecting the probe, Pi typically uses open flow cells which eliminate variability in pressure before it reaches the probe.

Flow

Whether the sample to the cell is pumped, gravity fed, or comes from a pressurised line, it is important that the flow is controlled to within a range of 350-1000ml per minute, to ensure that sufficient flow is reaching the sensor and to prevent the flow cell overflowing.


If the flow to the cell is variable, Pi can provide a dole valve which controls the flow to approximately 500ml per minute, which prevents the cell from overflowing when pressure variations mean more flow than the cell can handle, while also ensuring adequate flow when the sample line flow/pressure reduces.

Airlocks

The outlet of the flow cell needs to be open to atmosphere, and completely unobstructed. Any system with a long outlet line (particularly flexible pipe) is prone to get airlocks, which will cause the cell to overflow. Outlets which are visually clear and even have water flowing through them, can be partially airlocked which causes backpressure to overflow the cell. This is very easy to diagnose as if you see the cell overflowing and remove the outlet pipe, you will see the cell go back to normal operations within approximately 10 seconds. If this is a persistent problem, consider putting in an air break using a commercially available tundish.

Outlets that do not go to drain

The water from a membraned sensor doesn’t have to go to drain. For processes where saving water is a high priority, a simple tank and pump system that will pump sample water back into your main process line will allow water losses to be reduced to almost zero. Pi’s CRIUS^®4.0 controller can be used to control this return process and ensure that this tank never overflows and can automatically drain itself periodically to avoid sediment build up.

What if things go wrong?

As any water engineer can tell you, no matter how well the system is designed, lines can clog, pumps can break and someone on site could fiddle with the settings. Pi recognises these challenges and has engineered solutions into our systems. All Pi membraned sensors have the option to be able to:

• Have a flow switch to detect sample flow loss.
• Use dosing overfeed protection to protect against clogged dosing lines or pump failure.
• Have remote access for SMS or email alarms.
• Use relays to trigger beacons or sirens for alarms or control valves and pumps.
• Customise user security levels to control who can change what settings.
• Use status logs that show what happened to the system and when.

Closed Flow Cells

For membraned sensors, the best way of housing a membraned sensor is with an open flow cell. There are some occasions where this solution just isn’t practicable and in those instances the closed flow cells from Pi, which can take an overpressure of up to 3 bar, are the best solution.